1. The bum in oxygen to form water and carbon (iv) oxide
CH4(g) + 2O2(g) → CO2(g) + 2H2O(L)
2. They are undergo substitution reaction with chlorine in presence of ultraviolet light
CH4(g) + CL2(g) → CH2CL2(g) + HCL(g)
CH2CL2(g) + CL2(g) → CH2CL2(g) + HCL(g)
CH2CL2(g) + CL2(g) → CHCL3(L) + HCL(g)
CHCL3(L) + CL2(g) → CCL4(L) + HCL(g)